سامانه مدیریت نشریات علمی دانشگاه دامغان

شاه‌حسینی, مجید, دولتی ارده‌جانی, فرامرز, امینی, مهدی, ابراهیمی, لونا. (1399). شناسایی کانی‌های تازه تشکیل در شرایط اسیدی و اقلیم گرم و خشک، مطالعه موردی: انباشته کم-عیار معدن مس میدوک. مجله زمین شیمی ایران, 28(1), 159-170. doi: 10.29252/ijcm.28.1.159
مجید شاه‌حسینی; فرامرز دولتی ارده‌جانی; مهدی امینی; لونا ابراهیمی. "شناسایی کانی‌های تازه تشکیل در شرایط اسیدی و اقلیم گرم و خشک، مطالعه موردی: انباشته کم-عیار معدن مس میدوک". مجله زمین شیمی ایران, 28, 1, 1399, 159-170. doi: 10.29252/ijcm.28.1.159
شاه‌حسینی, مجید, دولتی ارده‌جانی, فرامرز, امینی, مهدی, ابراهیمی, لونا. (1399). 'شناسایی کانی‌های تازه تشکیل در شرایط اسیدی و اقلیم گرم و خشک، مطالعه موردی: انباشته کم-عیار معدن مس میدوک', مجله زمین شیمی ایران, 28(1), pp. 159-170. doi: 10.29252/ijcm.28.1.159
شاه‌حسینی, مجید, دولتی ارده‌جانی, فرامرز, امینی, مهدی, ابراهیمی, لونا. شناسایی کانی‌های تازه تشکیل در شرایط اسیدی و اقلیم گرم و خشک، مطالعه موردی: انباشته کم-عیار معدن مس میدوک. مجله زمین شیمی ایران, 1399; 28(1): 159-170. doi: 10.29252/ijcm.28.1.159

شناسایی کانی‌های تازه تشکیل در شرایط اسیدی و اقلیم گرم و خشک، مطالعه موردی: انباشته کم-عیار معدن مس میدوک

مجله بلورشناسی و کانی شناسی ایران
مقاله 11، دوره 28، شماره 1 - شماره پیاپی 77، فروردین 1399، صفحه 159-170    اصل مقاله (7.54 M)
نوع مقاله: مقاله پژوهشی
شناسه دیجیتال (DOI): 10.29252/ijcm.28.1.159
نویسندگان
مجید شاه‌حسینی1؛ فرامرز دولتی ارده‌جانی* 1؛ مهدی امینی1؛ لونا ابراهیمی2
1پردیس دانشکده‌های فنی دانشگاه تهران
2مرکز تحقیق و توسعه
چکیده
کانی­های تازه تشکیل (ثانویه) در نتیجه فرآیندهای اکسایش، آبکافت، ترسیب و آب­زدایی در محیط زهاب اسیدی تشکیل می­شوند. رخداد کانی­های ثانویه همراه با انباشته شماره 7 در معدن مس پورفیری میدوک با استفاده از کانی­شناسی پراش پرتوی ایکس (XRD)، میکروسکوپ الکترونی روبشی (SEM) و قله­نگاری رامان (RS) بررسی شد. بررسی­های زمین ­شیمیایی شاخص اشباع و گونه­زایی بر آب منفذی شبیه­سازی شده از آزمون pH گِل اشباع انجام شد. مقادیر pH اسیدی (بین 47/1 تا 23/4)، غلظت بالای سولفات (بین 95/3 تا 286 گرم بر لیتر) و غلظت بالای آهن (9/120 تا 70860 میلی­گرم بر لیتر) در شیرابه بیانگر اکسایش سولفیدها به ویژه پیریت در انباشته است. کمپلکس FeSO4+ به عنوان گونه غالب آهن سه ظرفیتی در فاز محلول شیرابه تعیین شد. بر اساس بررسی­های کانی­شناسی و زمین شیمیایی، کانی­های تازه تشکیل شامل کوکوئیمبیت، فری کوپیاپیت، پلمبوژاروسیت، روزنیت، آلونژن و بروکانتیت همراه با انباشته شناسایی شدند. نگه­داشت عناصر آرسنیک، سرب و مس توسط سولفات­های آهن به ویژه کوکوئیمبیت در انباشته تایید گردید. نتایج این پژوهش می­تواند در طراحی و گسترش برنامه­ جامع مدیریت زیست­محیطی مناطق معدنی مورد استفاده قرار گیرد.    
کلیدواژه‌ها
کانی‌های تازه تشکیل؛ اکسایش پیریت؛ سولفات آهن؛ قله نگاری رامان؛ انباشته کم-عیار مس
مراجع
  1. [1] INAP, "The International Network for Acid Prevention. Global Acid Rock Drainage Guide (GARD Guide)", 2009, <http://www.gardguide.com/>.
  2. [1] INAP, "The International Network for Acid Prevention. Global Acid Rock Drainage Guide (GARD Guide)", 2009, <http://www.gardguide.com/>.
  3. [2] Buzatu A., Dill H.G., Buzgar N., Damian G., Maftei A.E., Apopei A.I., "Efflorescent sulfates from Baia Sprie mining area (Romania) - Acid mine drainage and climatological approach", Science of the Total Environment 542 (2016) 629-641. [DOI:10.1016/j.scitotenv.2015.10.139]
  4. [2] Buzatu A., Dill H.G., Buzgar N., Damian G., Maftei A.E., Apopei A.I., "Efflorescent sulfates from Baia Sprie mining area (Romania) - Acid mine drainage and climatological approach", Science of the Total Environment 542 (2016) 629-641. [DOI:10.1016/j.scitotenv.2015.10.139]
  5. [3] Maki Zadeh M. A., Taghipour B., Salafzoon M., Reza Zadeh H., "Mineralogy and geochemistry of the hydrate sulfate minerals in relation to the black shales, Qroqchy, Mymeh, Isfahan", Iranian Journal of Crystallography and Mineralogy 24 (3) (2016) 595-604.
  6. [3] Maki Zadeh M. A., Taghipour B., Salafzoon M., Reza Zadeh H., "Mineralogy and geochemistry of the hydrate sulfate minerals in relation to the black shales, Qroqchy, Mymeh, Isfahan", Iranian Journal of Crystallography and Mineralogy 24 (3) (2016) 595-604.
  7. [4] Bigham J.M., Nordstrom D.K., "Iron and aluminum hydroxysulfates from acid sulfate waters", Review in Mineralogy and Geochemistry 40 (2000) 351-403 [DOI:10.2138/rmg.2000.40.7]
  8. [4] Bigham J.M., Nordstrom D.K., "Iron and aluminum hydroxysulfates from acid sulfate waters", Review in Mineralogy and Geochemistry 40 (2000) 351-403 [DOI:10.2138/rmg.2000.40.7]
  9. [5] Bigham J.M., Schwertmann U., Traina S.J., Winland R.L., Wolf M., "Schwertmannite and the chemical modeling of iron in acid sulfate waters", Geochimica Cosmochimica Acta 60 (1996) 2111-2121 [DOI:10.1016/0016-7037(96)00091-9]
  10. [5] Bigham J.M., Schwertmann U., Traina S.J., Winland R.L., Wolf M., "Schwertmannite and the chemical modeling of iron in acid sulfate waters", Geochimica Cosmochimica Acta 60 (1996) 2111-2121 [DOI:10.1016/0016-7037(96)00091-9]
  11. [6] Dold B., "Acid rock drainage prediction: A critical review", Journal of Geochemical Exploration 172 (2017) 120-132. [DOI:10.1016/j.gexplo.2016.09.014]
  12. [6] Dold B., "Acid rock drainage prediction: A critical review", Journal of Geochemical Exploration 172 (2017) 120-132. [DOI:10.1016/j.gexplo.2016.09.014]
  13. [7] Carrero S. Pérez-López R., Fernandez-Martinez A., Cruz-Hernández P., Agnieszka C., Poulain A., "The potential role of aluminium hydroxysulphates in the removal of contaminants in acid mine drainage", Chemical Geology 417 (2015) 414-423. [DOI:10.1016/j.chemgeo.2015.10.020]
  14. [7] Carrero S. Pérez-López R., Fernandez-Martinez A., Cruz-Hernández P., Agnieszka C., Poulain A., "The potential role of aluminium hydroxysulphates in the removal of contaminants in acid mine drainage", Chemical Geology 417 (2015) 414-423. [DOI:10.1016/j.chemgeo.2015.10.020]
  15. [8] Jamieson H. E., Robinson C., Alpers C. N., McCleskey R. B., Nordstrom D. K., Peterson R. C., "Major and trace element composition of copiapite-group minerals and coexisting water from the Richmond mine, Iron Mountain, California", Chemical Geology 215 (2005) 387-405 [DOI:10.1016/j.chemgeo.2004.10.001]
  16. [8] Jamieson H. E., Robinson C., Alpers C. N., McCleskey R. B., Nordstrom D. K., Peterson R. C., "Major and trace element composition of copiapite-group minerals and coexisting water from the Richmond mine, Iron Mountain, California", Chemical Geology 215 (2005) 387-405 [DOI:10.1016/j.chemgeo.2004.10.001]
  17. [9] Klingelhöfer G., Morris R. V., Bernhardt B., Schröder C., Rodionov D. S., de Souza Jr. P. A., Yen A., Gellert R., Evlanov E. N., Zubkov B., Foh J., Bonnes U., Kankeleit E., Gütlich P., Ming D. W., Renz F., Wdowiak T., Squyres S. W., Arvidson R. E., "Jarosite and Hematite at Meridiani Planum from Opportunity's Mössbauer Spectrometer", Science 306 (2004) 5702 1740-1745 [DOI:10.1126/science.1104653]
  18. [9] Klingelhöfer G., Morris R. V., Bernhardt B., Schröder C., Rodionov D. S., de Souza Jr. P. A., Yen A., Gellert R., Evlanov E. N., Zubkov B., Foh J., Bonnes U., Kankeleit E., Gütlich P., Ming D. W., Renz F., Wdowiak T., Squyres S. W., Arvidson R. E., "Jarosite and Hematite at Meridiani Planum from Opportunity's Mössbauer Spectrometer", Science 306 (2004) 5702 1740-1745 [DOI:10.1126/science.1104653]
  19. [10] Shi X-Zh., Lau I. C., Aspandiar M., "Comparison of PLSR modelling and indicative mineral mapping of airborne hyperspectral imagery for acid sulphate soil assessmen", International Journal of Remote Sensing 35 (2014) 1309-1330 [DOI:10.1080/01431161.2013.876121]
  20. [10] Shi X-Zh., Lau I. C., Aspandiar M., "Comparison of PLSR modelling and indicative mineral mapping of airborne hyperspectral imagery for acid sulphate soil assessmen", International Journal of Remote Sensing 35 (2014) 1309-1330 [DOI:10.1080/01431161.2013.876121]
  21. [11] Zabcic N., Rivard B., Ong C., Mueller A., "Using airborne hyperspectral data to characterize the surface pH and mineralogy of pyrite mine tailings", International Journal of Applied Earth Obseravation and Geoinformation 32 (2014) 152-162 [DOI:10.1016/j.jag.2014.04.008]
  22. [11] Zabcic N., Rivard B., Ong C., Mueller A., "Using airborne hyperspectral data to characterize the surface pH and mineralogy of pyrite mine tailings", International Journal of Applied Earth Obseravation and Geoinformation 32 (2014) 152-162 [DOI:10.1016/j.jag.2014.04.008]
  23. [12] Civeira M., Oliveira M. L. S., Hower J. C., Agudelo-Castañeda D. M., Taffarel Silvio R., Ramos C. G., Kautzmann R. M., Silva L. F. O., "Modification, adsorption, and geochemistry processes on altered minerals and amorphous phases on the nanometer scale: examples from copper mining refuse, Touro, Spain", Environental Science Pollutant Research 23 (2016) 6535-6545 [DOI:10.1007/s11356-015-5885-5]
  24. [12] Civeira M., Oliveira M. L. S., Hower J. C., Agudelo-Castañeda D. M., Taffarel Silvio R., Ramos C. G., Kautzmann R. M., Silva L. F. O., "Modification, adsorption, and geochemistry processes on altered minerals and amorphous phases on the nanometer scale: examples from copper mining refuse, Touro, Spain", Environental Science Pollutant Research 23 (2016) 6535-6545 [DOI:10.1007/s11356-015-5885-5]
  25. [13] Sobron P., Alpers C. N., "Raman Spectroscopy of Efflorescent Sulfate Salts from Iron Mountain Mine Superfund Site, California", ASTROBIOLOGY 13 (2013) 3 270-278. [DOI:10.1089/ast.2012.0908]
  26. [13] Sobron P., Alpers C. N., "Raman Spectroscopy of Efflorescent Sulfate Salts from Iron Mountain Mine Superfund Site, California", ASTROBIOLOGY 13 (2013) 3 270-278. [DOI:10.1089/ast.2012.0908]
  27. [14] Parviainen A., Cruz-Hernández P., Pérez-López R., Nieto J. M., Delgado-López J. M., "Raman identification of Fe precipitates and evaluation of As fate during phase transformation in Tinto and Odiel River Basins", Chemical Geology 398 (2015) 22-31. [DOI:10.1016/j.chemgeo.2015.01.022]
  28. [14] Parviainen A., Cruz-Hernández P., Pérez-López R., Nieto J. M., Delgado-López J. M., "Raman identification of Fe precipitates and evaluation of As fate during phase transformation in Tinto and Odiel River Basins", Chemical Geology 398 (2015) 22-31. [DOI:10.1016/j.chemgeo.2015.01.022]
  29. [15] Richards J. P., Sholeh A., "The Tethyan Tectonic History and Cu-Au Metallogeny of Iran", Economic Geologist Special Publication, (2016) 193-212.
  30. [15] Richards J. P., Sholeh A., "The Tethyan Tectonic History and Cu-Au Metallogeny of Iran", Economic Geologist Special Publication, (2016) 193-212.
  31. [16] Shahhosseini M., Doulati Ardejani F., Amini M., Ebrahimi L., Mohebi Poorkani A., "Environmental geochemistry of As and Pb in a copper low-grade dump, Miduk copper mine, Kerman province, SE Iran", Journal of Geochemical Exploration 198 (2019) 54-70. [DOI:10.1016/j.gexplo.2018.12.013]
  32. [16] Shahhosseini M., Doulati Ardejani F., Amini M., Ebrahimi L., Mohebi Poorkani A., "Environmental geochemistry of As and Pb in a copper low-grade dump, Miduk copper mine, Kerman province, SE Iran", Journal of Geochemical Exploration 198 (2019) 54-70. [DOI:10.1016/j.gexplo.2018.12.013]
  33. [17] Smart R., Skinner B., Levay G., Gerson A., Thomas J., Sobobieraj H., Schumann R., Weisener C., Weber P., Miller S., Stewart, W., "ARD test handbook: project P387A prediction and kinetic control of acid mine drainage", In: Predict. Kinet. Control Acid Mine Drainage, (2002) Proj. P387A 42.
  34. [17] Smart R., Skinner B., Levay G., Gerson A., Thomas J., Sobobieraj H., Schumann R., Weisener C., Weber P., Miller S., Stewart, W., "ARD test handbook: project P387A prediction and kinetic control of acid mine drainage", In: Predict. Kinet. Control Acid Mine Drainage, (2002) Proj. P387A 42.
  35. [18] Rull F., Guerrero J., Venegas G., Gázquez F., Medina J., "Spectroscopic Raman study of sulphate precipitation sequence in Rio Tinto mining district (SW Spain)", Environmental Science Pollution Research 21 (2014) 6783-6792. [DOI:10.1007/s11356-013-1927-z]
  36. [18] Rull F., Guerrero J., Venegas G., Gázquez F., Medina J., "Spectroscopic Raman study of sulphate precipitation sequence in Rio Tinto mining district (SW Spain)", Environmental Science Pollution Research 21 (2014) 6783-6792. [DOI:10.1007/s11356-013-1927-z]
  37. [19] Parkhurst D.L., Appelo C.A.J., "PHREEQC (Version 3)-a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations", In: Model. Tech. B. (2013). [DOI:10.3133/tm6A43]
  38. [19] Parkhurst D.L., Appelo C.A.J., "PHREEQC (Version 3)-a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations", In: Model. Tech. B. (2013). [DOI:10.3133/tm6A43]
  39. [20] Elisa M., Gomes P., Favas P. J.C., "Mineralogical controls on mine drainage of the abandoned Ervedosa tin mine in north-eastern Portugal", Applied Geochemistry 21(2006) 1322-1334 [DOI:10.1016/j.apgeochem.2006.06.007]
  40. [20] Elisa M., Gomes P., Favas P. J.C., "Mineralogical controls on mine drainage of the abandoned Ervedosa tin mine in north-eastern Portugal", Applied Geochemistry 21(2006) 1322-1334 [DOI:10.1016/j.apgeochem.2006.06.007]
  41. [21] Romero A., Gonzalez I., Galan E., "The role of efflorescent sulfates in the storage of trace elements in stream waters polluted by acid mine-drainage: The case of Pena Del Hierro, southwestern Spain", The Canadian Mineralogist 44 (2006) 1431-1446. [DOI:10.2113/gscanmin.44.6.1431]
  42. [21] Romero A., Gonzalez I., Galan E., "The role of efflorescent sulfates in the storage of trace elements in stream waters polluted by acid mine-drainage: The case of Pena Del Hierro, southwestern Spain", The Canadian Mineralogist 44 (2006) 1431-1446. [DOI:10.2113/gscanmin.44.6.1431]
  43. [22] Noli F., Misaelides P., Hatzidimitriou A., Pavlidou E., Kokkoris M., "Investigation of artificially produced and natural copper patina layers" Journal of Material Chemistry 13 (2003) 114-120. [DOI:10.1039/b206773k]
  44. [22] Noli F., Misaelides P., Hatzidimitriou A., Pavlidou E., Kokkoris M., "Investigation of artificially produced and natural copper patina layers" Journal of Material Chemistry 13 (2003) 114-120. [DOI:10.1039/b206773k]
  45. [23] Frost R. L. Zigovecki Gobac Z., López A., Xi Y., Scholz R., Lana C., Malena Fernandes Lima R., "Characterization of the sulphate mineral coquimbite, a secondary iron sulphate from Javier Ortega mine, Lucanas Province, Peru - Using infrared, Raman spectroscopy and thermogravimetry", Journal of Molecular Structure 1063 (2014) 251-258 [DOI:10.1016/j.molstruc.2014.01.086]
  46. [23] Frost R. L. Zigovecki Gobac Z., López A., Xi Y., Scholz R., Lana C., Malena Fernandes Lima R., "Characterization of the sulphate mineral coquimbite, a secondary iron sulphate from Javier Ortega mine, Lucanas Province, Peru - Using infrared, Raman spectroscopy and thermogravimetry", Journal of Molecular Structure 1063 (2014) 251-258 [DOI:10.1016/j.molstruc.2014.01.086]
  47. [24] Frost R. L., Wills R. A., Weier M. L., Martens W., Mills S. "A Raman spectroscopic study of selected natural jarosites", Spectrochimica Acta Part A 63 (2006) 1-8 [DOI:10.1016/j.saa.2005.03.034]
  48. [24] Frost R. L., Wills R. A., Weier M. L., Martens W., Mills S. "A Raman spectroscopic study of selected natural jarosites", Spectrochimica Acta Part A 63 (2006) 1-8 [DOI:10.1016/j.saa.2005.03.034]
  49. [25] Kosek F., Culka A., Zacek V., Laufek F., Skoda R., Jehlicka J., "Native alunogen: A Raman spectroscopic study of a well-described specimen", Journal of Molecular Structure 1157 (2018) 191-200 [DOI:10.1016/j.molstruc.2017.12.021]
  50. [25] Kosek F., Culka A., Zacek V., Laufek F., Skoda R., Jehlicka J., "Native alunogen: A Raman spectroscopic study of a well-described specimen", Journal of Molecular Structure 1157 (2018) 191-200 [DOI:10.1016/j.molstruc.2017.12.021]
  51. [26] Apopei A. I., Buzgar N., Gheorghe D., Buzatu A., "The Raman study of weathering minerals from the Coranda-Hondol open pit (Certej gold-silver deposit) and their photochemical degradation products under laser irradiation", The Canadian Mineralogist 52 (2014) 1027-1038. [DOI:10.3749/canmin.1300054]
  52. [26] Apopei A. I., Buzgar N., Gheorghe D., Buzatu A., "The Raman study of weathering minerals from the Coranda-Hondol open pit (Certej gold-silver deposit) and their photochemical degradation products under laser irradiation", The Canadian Mineralogist 52 (2014) 1027-1038. [DOI:10.3749/canmin.1300054]
  53. [27] Quispe D., Pérez-López R., Acero P., Ayora C., Nieto J. M., "The role of mineralogy on element mobility in two sulfide mine tailings from the Iberian Pyrite Belt (SW Spain)" Chemical Geology 345 (2013) 119-129. [DOI:10.1016/j.chemgeo.2013.03.002]
  54. [27] Quispe D., Pérez-López R., Acero P., Ayora C., Nieto J. M., "The role of mineralogy on element mobility in two sulfide mine tailings from the Iberian Pyrite Belt (SW Spain)" Chemical Geology 345 (2013) 119-129. [DOI:10.1016/j.chemgeo.2013.03.002]
  55. [28] Liua Q., Chena B., Haderleinc S., Gopalakrishnan G., Zhou Y. "Characteristics and environmental response of secondary minerals in AMD from Dabaoshan Mine, South China", Ecotoxicology and Environmental Safety 155 (2018) 50-58. [DOI:10.1016/j.ecoenv.2018.02.017]
  56. [28] Liua Q., Chena B., Haderleinc S., Gopalakrishnan G., Zhou Y. "Characteristics and environmental response of secondary minerals in AMD from Dabaoshan Mine, South China", Ecotoxicology and Environmental Safety 155 (2018) 50-58. [DOI:10.1016/j.ecoenv.2018.02.017]
  57. [29] Kosek F., Culka A., Jehlicka J., "Raman spectroscopic study of six synthetic anhydrous sulfates relevant to the mineralogy of fumaroles", Journal of Raman Spectroscopy (2018) 1-12. [DOI:10.1002/jrs.5363]
  58. [29] Kosek F., Culka A., Jehlicka J., "Raman spectroscopic study of six synthetic anhydrous sulfates relevant to the mineralogy of fumaroles", Journal of Raman Spectroscopy (2018) 1-12. [DOI:10.1002/jrs.5363]
  59. [30] Kahlenberg V., Braun D.E., Kruger H., Schmidmair D., Orlova M., "Temperatureand moisture-dependent studies on alunogen and the crystal structure of meta-alunogen determined from laboratory powder diffraction data", Physics Chemistry and Mineralogy 44 (2017) 95-107. [DOI:10.1007/s00269-016-0840-7]
  60. [30] Kahlenberg V., Braun D.E., Kruger H., Schmidmair D., Orlova M., "Temperatureand moisture-dependent studies on alunogen and the crystal structure of meta-alunogen determined from laboratory powder diffraction data", Physics Chemistry and Mineralogy 44 (2017) 95-107. [DOI:10.1007/s00269-016-0840-7]
  61. [31] Wang A., Zhou Y., "Experimental comparison of the pathways and rates of the dehydration of Al-, Fe-, Mg- and Ca-sulfates under Mars relevant conditions", Icarus 234 (2014) 162-173. [DOI:10.1016/j.icarus.2014.02.003]
  62. [31] Wang A., Zhou Y., "Experimental comparison of the pathways and rates of the dehydration of Al-, Fe-, Mg- and Ca-sulfates under Mars relevant conditions", Icarus 234 (2014) 162-173. [DOI:10.1016/j.icarus.2014.02.003]
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